Next-generation energy for wearable device: bioinspired, eco-friendly, and felxible all-solid-state supercapacitors
Using the concept of bionics and circular economy to develop low-cost and high -performance flexible electrodes and ionic liquid polyelectrolytes for all solid-state flexible supercapacitors. This type of flexible electrode has excellent dimensional stability and electrochemical characteristics. The gel-state polyelectrolytes can be used with metal oxide electrodes to provide high scalability, low cost, and high efficiency at high temperatures.
We used in-situ X-ray absorption near-edge spectroscopy to understand energy storage mechanism of the flexible all-solid-state supercapactors. Experimental results from synchrotron based X-ray techniques showed that the electrode’s structure features a 3D ant-nest-like framework composed of 2D nacre-like clay nanosheets, i.e. hierarchical layers-within-networks structure. We have also discovery a series of ionic liquid polyelectrolytes, which have good stability and energy storage performance in high-temperature tests and rapid charge-discharge tests.
We propose an environmentally friendly, low-cost, and scalable method for manufacturing structural electrodes and a low-cost ionic liquid polyelectrolyte. Flexible all-solid-state supercapacitors combined with this series of polyelectrolytes have excellent performance under high temperature operation, which can solve the high temperature generated from excessive electronic devices. Our polyelectrolytes also solve safety concerns, because it is a gel state polyelectrolyte can improve electrolyte leakage and other problems.
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NSRRC, the biggest large-scale shared research facility in Taiwan, currently operates two accelerators, the Taiwan Light Source (TLS) and the Taiwan Photon Source (TPS). TLS, of beam energy 1.5 GeV and circumference 120 meters, is the first third-generation synchrotron light source facility in Asia and the third globally. It has opened to users since October, 1993. The best optimized energy range of synchrotron light from TLS is between vacuum ultraviolet light and soft X-rays. The TPS, of circumference 518.4 meters, is one of the brightest synchrotron light sources in the world. It began its operation in September, 2016. To meet the demands from modern technologies and pioneer sciences for higher-brightness light beams, such as biomedicine and nanoscience, it is equipped with a low-emittance synchrotron storage ring and booster synchrotron producing a beam of energy 3 GeV. It generates X-rays in the higher energy range from soft X-rays to hard X-rays, and has a capacity of more than 40 beamlines. In addition, NSRRC built and operates two hard X-ray Taiwanese beamlines at SPring-8, Japan, as well as a cold neutron triple-axis spectrometer at the Australian Nuclear Science and Technology Organisation (ANSTO), under the international collaboration agreements. Scientists from around the world can access NSRRC’s facilities to explore the properties of materials in a wide range of disciplines through a competitive proposal process. Every year, over 2,000 users use NSRRC’s experimental facilities, which not only enable basic research, but also facilitate high-tech innovation. NSRRC possesses one of the most advanced synchrotron facilities in the world and its pioneering capabilities keep Taiwan at the forefront of scientific research.
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